Search results for "Atomic number"
showing 10 items of 65 documents
Direct mass measurements and ionization potential measurements of the actinides
2019
Abstract The precise determination of atomic and nuclear properties such as masses, differential charge radii, nuclear spins, electromagnetic moments and the ionization potential of the actinides has been extended to the late actinides in recent years. In particular, laser spectroscopy and mass spectrometry have reached the region of heavy actinides that can only be produced only at accelerator facilities. The new results provide deeper insight into the impact of relativistic effects on the atomic structure and the evolution of nuclear shell effects around the deformed neutron shell closure at N = 152. All these experimental activities have also opened the door to extend such measurements t…
Microscopic origin of the charge transfer in single crystals based on thiophene derivatives: A combined NEXAFS and density functional theory approach
2016
We have investigated the charge transfer mechanism in single crystals of DTBDT-TCNQ and DTBDT-F4TCNQ (where DTBDT is dithieno[2,3-d;2',3'-d'] benzo[1,2-b;4,5-b']dithiophene) using a combination of near-edge X-ray absorption spectroscopy (NEXAFS) and density functional theory calculations (DFT) including final state effects beyond the sudden state approximation. In particular, we find that a description that considers the partial screening of the electron-hole Coulomb correlation on a static level as well as the rearrangement of electronic density shows excellent agreement with experiment and allows to uncover the details of the charge transfer mechanism in DTBDT-TCNQ and DTBDT-F4 TCNQ, as w…
Efficacy of single-source rapid kV-switching dual-energy CT for characterization of non-uric acid renal stones: a prospective ex vivo study using ant…
2019
Purpose To investigate the accuracy of rapid kV-switching single-source dual-energy computed tomography (rsDECT) for prediction of classes of non-uric-acid stones. Materials and methods Non-uric-acid renal stones retrieved via percutaneous nephrolithotomy were prospectively collected between January 2017 and February 2018 in a single institution. Only stones >= 5 mm and with pure composition (i.e., >= 80% composed of one component) were included. Stone composition was determined using Fourier Transform Infrared Spectroscopy. The stones were scanned in 32-cm-wide anthropomorphic whole-body phantom using rsDECT. The effective atomic number (Zeff), the attenuation at 40 keV (HU40), 70 ke…
ESR response to gamma-rays of alanine pellets containing B(OH)3 or Gd2O3.
2007
ESR response to gamma-irradiation (1-50 Gy) of blends containing alanine and either B(OH)(3) or Gd(2)O(3) is reported. The sensitivity of the alanine--B(OH)(3) blend is comparable to the sensitivity of pure alanine, although its lowest detectable dose, LDD, is smaller ( approximately 1.3 Gy) than that of pure alanine ( approximately 2.9 Gy). Alanine with Gd(2)O(3) is about two times more sensitive than pure alanine, and its LDD is 0.8 Gy. The better sensitivity and LDD are probably due to the high atomic number (Z=64) of gadolinium, which enhances the interaction probability with photons and, consequently, the radical yield. This study suggests that other high-Z atoms may be useful for incr…
Prospects of Ion Chemical Reactions with Heavy Elements in the Gas Phase
2001
Heavy element chemistry is related to the fundamental interest that lies in exploring the upper limits of the periodic table. Chemical properties of the heaviest elements have already been studied at single atoms in aqueous solutions and in the gas phase up to an atomic number Z = 107. These techniques allow to study nuclides with half lives as short as about 1 s. Next generation chemistry experiments could be envisaged with an ion trap technique already developed for stable isotopes. At very low production rates in the order of 1 per 100 s and/or half lives as short as about 10 ms, the ion-molecule reactions can be studied in a buffer gas cell, in which the heavy elements are stopped and t…
Isotope-shift measurements of stable and short-lived lithium isotopes for nuclear-charge-radii determination
2010
Changes in the mean-square nuclear charge radii along the lithium isotopic chain were determined using a combination of precise isotope shift measurements and theoretical atomic structure calculations. Nuclear charge radii of light elements are of high interest due to the appearance of the nuclear halo phenomenon in this region of the nuclear chart. During the past years we have developed a new laser spectroscopic approach to determine the charge radii of lithium isotopes which combines high sensitivity, speed, and accuracy to measure the extremely small field shift of an 8 ms lifetime isotope with production rates on the order of only 10,000 atoms/s. The method was applied to all bound iso…
Analytic response relativistic coupled-cluster theory: the first application to indium isotope shifts
2019
With increasing demand for accurate calculation of isotope shifts of atomic systems for fundamental and nuclear structure research, an analytic energy derivative approach is presented in the relativistic coupled-cluster theory framework to determine the atomic field shift and mass shift factors. This approach allows the determination of expectation values of atomic operators, overcoming fundamental problems that are present in existing atomic physics methods, i.e. it satisfies the Hellmann-Feynman theorem, does not involve any non-terminating series, and is free from choice of any perturbative parameter. As a proof of concept, the developed analytic response relativistic coupled-cluster the…
Adsorption of 3d Transition Elements on a TiO2(110) Surface.
2008
International audience; A first-principles study on the adsorption of 3d transition metal atoms on a stoichiometric TiO2(110) surface is reported. For all 3d elements except Cu, the most stable on-surface adsorption site is a site where the adatom binds to two twofold and one threefold surface oxygen atoms. For Ti, V, and Cr, however, a subsurface site, where the adatom substitutes a sixfold Ti atom, is more stable. The adatoms are oxidized in all cases. The charge transfer to the substrate is larger for the substitutional site than for the on-surface adsorption sites and decreases with atomic number along the 3d series. The relative stabilities of the adsorption sites are discussed in term…
Separation of U(VI) and Th(IV) from Some Rare Earths by Thin Layer Chromatography with Di‐(2‐Ethylhexyl)‐Dithiophosphoric Acid on Silica Gel
2005
Abstract Separation of U(VI) and Th(IV) from some rare earths by TLC has been studied using silica gel H and silica gel H impregnated with ammonium nitrate as the stationary phase. The solvent mixture ethyl‐methyl‐ketone–tetrahydrofuran (6∶3, v/v) containing di-(2‐ethylhexyl)-dithiophosphoric acid was used as the mobile phase. When silica gel H impregnated with 2.5 M NH4NO3 was used as stationary phase, the resolution was much improved and the separation of rare earths from each other was also achieved. The tetrad‐effect was observed in variation of R*m versus the atomic number of rare earths.
Probing number squeezing of ultracold atoms across the superfluid-Mott insulator transition.
2005
The evolution of on-site number fluctuations of ultracold atoms in optical lattices is experimentally investigated by monitoring the suppression of spin-changing collisions across the superfluid-Mott insulator transition. For low atom numbers, corresponding to an average filling factor close to unity, large on-site number fluctuations are necessary for spin-changing collisions to occur. The continuous suppression of spin-changing collisions is thus a direct evidence for the emergence of number-squeezed states. In the Mott insulator regime, we find that spin-changing collisions are suppressed until a threshold atom number, consistent with the number where a Mott plateau with doubly-occupied …